The name describes a style of proof system, not one fixed choice of axioms and rules. Different choices can prove the same formulas; the propositional Hilbert calculus is one such choice.
Contrast with Other Calculi
Hilbert calculus: derives formulas; logical principles are primarily encoded in axiom schemata.
Sequent calculus: derives sequents , with assumptions and possible conclusions ; logical principles are primarily encoded in connective-specific left and right rules.
Natural deduction: derives formulas using introduction and elimination rules for connectives; temporary assumptions can be discharged, for example when deriving from a derivation of under assumption .
Resolution calculus: combines clauses by eliminating complementary literals; deriving the empty clause establishes that the input clauses are unsatisfiable.
Logical structure is encoded in axioms
In the propositional system, every non-axiom line uses the same rule: modus ponens. Reasoning about different connectives comes from choosing axiom instances, rather than applying separate rules for each connective.
Derived inference rules can shorten proofs: each application stands for a derivation using the primitive axioms and rules. Introduction and elimination rules can be used this way without becoming primitive rules of the calculus.